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Ziegler‐Natta oligomerization of 1‐alkenes: a catalyst's “fingerprint”, 1. Hydrooligomerization of propene in the presence of a highly isospecific MgCl~2~‐supported catalyst by Busico, Vincenzo ;Cipullo, Roberta ;Corradini, Paolo is a Chemistry article available to read on EtoBox.

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## Abstract The stereochemistry of propene polyinsertion catalyzed by a highly isospecific MgCl~2~‐supported Ziegler‐Natta system was investigated by means of the gas chromatographic/mass spectrometric (GC‐MS) characterization of the saturated oligomers (hydrooligomers) formed in the presence of H~2~ at high pressure (as a chain transfer agent). It was shown that the hydrooligomer distribution is a true catalyst “fingerprint”, from which, in case of systems with (prevailingly) a single type of active centres, both the regio‐ and the stereospecificity of polyinsertion can be quantitatively evaluated.

Who reads Ziegler‐Natta oligomerization of 1‐alkenes: a catalyst's “fingerprint”, 1. Hydrooligomerization of propene in the presence of a highly isospecific MgCl~2~‐supported catalyst?

Author

Busico, Vincenzo ;Cipullo, Roberta ;Corradini, Paolo

Publisher

Wiley (John Wiley & Sons); Wiley (ISSN 0025-116X)

Published

1993

Language

EN

Field

Chemistry (Physical Sciences)