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-Chloroalkyllithium sulfonic acid derivatives by W.E. Truce; L.W. Christensen is a Chemistry article available to read on EtoBox.

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Simple a-haloalkyllithiums have been shown to exist as stable entidmsat low temperatures (l-5). However little data have been accumulated on u-haloalkyllithiums bearing a carbanionstabilizing group on the z-carbon. Our interest in the synthetic utility of sulfur-stabilized carbanions (6-81, coupled with a recent communication on u-halolithi\rm sulfoxidee (9) prompts us to report the first preparation and characterization of a-chloroalkyllithium sulfonic acid derivatives. THF @' ClCH2S02-Y + n-BuLi \_78d LiCHClS02-Y a) Y=o; b) Y=GCH2C(CH3)3

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Author
W.E. Truce; L.W. Christensen
Publisher
Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
Published
1969
Language
ZU
Field
Chemistry (Physical Sciences)

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