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1,3-dipolar cycloaddition reactions of 1-aryl-N-methyl-2(1H-azol-1-yl)-ethanimine N-oxides to olefins by George B. Mullen; Grace A. Bennett; Patricia A. Swift; David M. Marinyak; Peter G. Dormer; Vassil St. Georgiev is a Chemistry article available to read on EtoBox.

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## Abstract The regio‐ and stereoselectivity of the 1,3‐dipolar cycloaddition reaction of 1‐aryl‐__N__‐methyl‐2‐(1__H__‐azol‐1‐yl)ethanimine __N__‐oxides 6 to monosubstituted olefins 7 were investigated. The reaction is regioselective, leading to the corresponding C‐5 substituted isoxazolidines 8/9 as __cis__/__trans__ diastereomeric mixtures. The __cis__ isomers, which are the predominant species of the mixtures, are readily separated by flash chromatography on neutral silica gel.

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Author

George B. Mullen; Grace A. Bennett; Patricia A. Swift; David M. Marinyak; Peter G. Dormer; Vassil St. Georgiev

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); VCH Verlagsgesellschaft; Wiley (ISSN 0947-3440)

Published

1990

Language

EN

Field

Chemistry (Physical Sciences)