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Comprehensive Organic Synthesis - Selectivity, strategy and efficiency in modern organic chemistry in 9 Vol. Volume 3 - Carbon-Carbon a σ-Bond Formation [reprint 1991] by Trost B.M., Fleming I., Pattenden G. (eds.) is a nonfiction available to read on EtoBox.
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Trost Barry M. Comprehensive Organic Synthesis - Selectivity, strategy and efficiency in modern organic chemistry in 9 Vol. Volume 3 - Carbon-Carbon a σ-Bond Formation [reprint 1991] 2005 [djvu 1179sc 1186c. 9.60mb]Volume 3 covers carbon-to-carbon single bond forming reactions involving sp 3, sp 2 and sp carbon centers, but only those which do not involve additions to C-X &pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of sp 3 carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to &agr;-bond formation, and involving all types of combinations of sp 3, sp 2 and sp carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon &agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based
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- Author
- Trost B.M., Fleming I., Pattenden G. (eds.)
- Publisher
- Pergamon Press
- Published
- 1991
- Language
- EN
- ISBN
- 9780080405964
- Category
- nonfiction
- Subjects
- Science, Chemistry, Mathematics
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