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BIOCHAR: CHEMICAL COMPOSITION, SOIL APPLICATIONS AND ECOLOGICAL IMPACTS 3 BIOCHAR: CHEMICAL COMPOSITION, SOIL APPLICATIONS AND ECOLOGICAL IMPACTS 5 NOTICE TO THE READER 6 CONTENTS 7 PREFACE 9 Chapter 1: PHYSICAL-CHEMICAL PROPERTIES OF SAWDUST BIOCHAR 13 ABSTRACT 13 1. INTRODUCTION 14 2. BIOCHAR PRODUCTION 15 3. MICRO-PHYSICAL STRUCTURE OF BIOCHAR 20 4. FUNCTIONAL GROUPS OF BIOCHAR 28 5. AAEM SPECIES OF BIOCHAR 42 CONCLUSION 48 REFERENCES 49 BIOGRAPHICAL SKETCH 54 Chapter 2: THE EFFECTS OF SWITCHGRASS-DERIVED BIOCHAR ON BIOENERGY CROP YIELD, PLANT COMPOSITION, AND SOIL PROPERTIES 59 ABSTRACT 60 INTRODUCTION 60 EXPERIMENTAL 63 RESULTS AND DISCUSSION 67 CONCLUSION 78 ACKNOWLEDGMENTS 79 REFERENCES 79 Chapter 3: CHANGES IN PHYTOAVAILABLE CONCENTRATIONS IN A MINE SOIL FOLLOWING THE APPLICATION OF TECHNOSOLS AND BIOCHAR WITH BRASSICA JUNCEA L. 85 ABSTRACT 85 1. INTRODUCTION 86 2. MATERIAL AND METHODS 88 3. RESULTS 93 4. DISCUSSION 105 CONCLUSION 109 REFERENCES 110 INDEX 115 Blank Page 2

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