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Comparison of Yttrium Binaphthylamido Alkyl and Amide Complexes for Enantioselective Intramolecular Hydroamination by Isabelle Aillaud; Jacqueline Collin; Jérôme Hannedouche; Emmanuelle Schulz; Alexander Trifonov is a Chemistry article available to read on EtoBox.
What is Comparison of Yttrium Binaphthylamido Alkyl and Amide Complexes for Enantioselective Intramolecular Hydroamination about?
A chiral trisamido yttrium complex Y[(R)-C 20 H 12 (NC 5 H 9 ) 2 ][NiPr 2 ][THF] 2 ÁLiCl coordinated by N-cyclopentyl binaphthylamine ligand has been prepared in situ and characterised by NMR spectroscopy. It has been revealed as an efficient catalyst for intramolecular hydroamination of aminoolefins. Comparison with neutral alkyl, ate alkyl or ate tetraamido complexes coordinated by the same ligand indicated that this complex was the most efficient catalyst of the series for its both activity and enantioselectivity values.
Who reads Comparison of Yttrium Binaphthylamido Alkyl and Amide Complexes for Enantioselective Intramolecular Hydroamination?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Isabelle Aillaud; Jacqueline Collin; Jérôme Hannedouche; Emmanuelle Schulz; Alexander Trifonov
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 2010
- Language
- EN
- Field
- Chemistry (Physical Sciences)