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The rotationally resolved spectra and pre-dissociation of CS2 of 210 nm band initiated from highly vibrationally excited levels by Heuri Tarng Liou; Kuang Lang Huang; Meng Chun Chen is a Physics and Astronomy article available to read on EtoBox.

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The jet-cooled rotationally resolved spectra of the pre-dissociation band E~ of the ~B2(IE~+) state of CS 2 at 210 nm, which were initiated from highly vibrationally excited levels of the ground electronic state X~E~, were recorded using the technique of stimulated emission pumping to prepare the initial levels. The band origin and the rotational constants B, D are 47561.749(12) cm-t and 0.09903( 19), 1.4(4.4)X 10 -6 cm-1, respectively. Additionally, state-prepared photo-dissociation was demonstrated by this technique. The pre-dissociation rate initiated from the level of (3 18 0) X 132÷ is two times faster g than that of (0 0 0).

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Author

Heuri Tarng Liou; Kuang Lang Huang; Meng Chun Chen

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)

Published

1997

Language

EN

Field

Physics and Astronomy (Physical Sciences)