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Reactions of 1,4,7-trithiacyclononane, [9]aneS3, with early transition metal halides: synthesis and X-ray structure of {Fe([9]aneS3)2}[Sb2Cl8] by Gerald R. Willey; Janet Palin; Miles T. Lakin; Nathaniel W. Alcock is a Chemistry article available to read on EtoBox.

What is Reactions of 1,4,7-trithiacyclononane, [9]aneS3, with early transition metal halides: synthesis and X-ray structure of {Fe([9]aneS3)2}[Sb2Cl8] about?

The reactions of titanium(III) and (IV) chlorides with the crown thioether [93aneS3 were investigated. [TiCt 3-(MeCN)3 ] gives a purple 1:1 adduet with a proposed octahedral structure involving tridentate foe-attachment of the ligand. With [TiClg(MeCN)2] the identity of the yellow 1:1 adduct obtained is discussed in terms of a six-coordinate species with bidentate ligand chelation. The title compound was isolated from the reactions of [9laneS 3 with [TiC13(MeCN) 3] [SbC16] (by accident) and iron filings/SbCl5 in MeCN solution and characterised crystallographically. The cation has two macrocyclic ligands coordinated facially to a six-coordinate Fe z § ion; the anion comprises dimeric [(SbC14)2] units linked together into a polymeric chain by weak halogen bridging.

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Author

Gerald R. Willey; Janet Palin; Miles T. Lakin; Nathaniel W. Alcock

Publisher

Springer; Springer-Verlag; Kluwer Academic Publishers; Springer Science and Business Media LLC; Society for Mining, Metallurgy and Exploration Inc. (ISSN 0340-4285)

Published

1994

Language

EN

Field

Chemistry (Physical Sciences)