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Role of interfacial energy anisotropy in dendrite orientation in Al-Zn alloys: A phase field study 1 1 Introduction 2 2 Phase field method 2 3 Simulation results and analysis 3 3.1 Typical and atypical dendrite pattern 3 3.2 Mechanism of dendrite orientation transition 4 3.3 Solute segregation in ⟨100⟩ orientation dendrite 6 3.3.1 Liquid holes and solidification sequence 6 3.3.2 Dendrite growth and solute segregation with initial supersaturation 6 3.4 Liquid groove in ⟨110⟩ orientation 7 3.5 A simple experimental verification 8 4 Discussions 9 4.1 Anisotropy of interface energy 9 4.2 Multiple sources of anisotropy 10 4.2.1 Extrinsic anisotropy 10 4.2.2 Elastic anisotropy 10 4.2.3 Anisotropy of solidified dendrites 11 4.3 Prospects 12 5 Conclusions 12 Declaration of Competing Interest 12 ack21 12 Acknowledgements 12 Data Availability 12 Appendix A Supplementary material 12 References 12
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