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The document discusses the direct synthesis of dimethyl carbonate using carbon dioxide as a solvent and reagent. It characterized a new organotin oxide complex with 10 tin atoms that could be an intermediate species. The highest dimethyl carbonate yield occurred under 20 MPa pressure in a supercritical carbon dioxide medium. Preliminary kinetics experiments showed a positive order in carbon dioxide and first-order dependence on the organotin precursor. Further kinetics work aims to determine the rate-limiti

Author

maito2270

Language

EN