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Vibrational effects in the Si 2p pre-edge photoabsorption spectroscopy of SiH4, SiD4, Si2H6 and Si3H8 by D.G.J. Sutherland; G.M. Bancroft; J.D. Bozek; K.H. Tan is a Physics and Astronomy article available to read on EtoBox.

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High-resolution (0.05 eV) Si 2p pre-edge photoabsorption spectra of SiH,, SiD,, S&H6 and S&Ha have been recorded. The spectra show a large number of peaks due to Si 2pdRydberg transitions, along with rich vibrational structure. The spectrum of SiD4 has been very useful in determining the exact positions of Rydberg states and vibrational excitations from both symmetric and asymmetric Si-H (D) vibrational modes. The spectra of disilane and trisilane are very similar to each other, although the vibrational effects are much more apparent in the spectrum of disilane where both asymmetric Si-H and symmetric Si-Si vibrational progressions have been observed.

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Author

D.G.J. Sutherland; G.M. Bancroft; J.D. Bozek; K.H. Tan

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)

Published

1992

Language

EN

Field

Physics and Astronomy (Physical Sciences)