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1) For cyclic ketones like norbornanone and cyclohexanone, computational studies found that deprotonation occurs more readily at exo protons rather than endo protons due to better stereoelectronic alignment with the carbonyl group. 2) For cyclohexanone, removal of an axial proton is favored over an equatorial proton by 2.8 kcal/mol due to less torsional strain. 3) For nitroalkanes, additional alkyl substituents retard the rate of deprotonation but make the equilibrium more favorable. Steric effects dominat

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panda biru

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EN