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The study presents a novel photothermal dual-responsive catalyst, ZnNCN/NaK-CN, which enhances CO2 cycloaddition with epoxides by utilizing a built-in electric field for charge migration. This catalyst achieves high productivity and yields under mild conditions, significantly outperforming traditional thermal methods. Mechanistic insights reveal that photogenerated electrons facilitate CO2 activation, providing a new framework for efficient CO2 conversion.
- Author
- Mohammad Saud Athar
- Language
- EN