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Synthesis, Characterization of a Novel 1,2,4‐Thiotriazine Derivative (CAMTTO), and Copper(I) and Silver(I) Complexes thereof (CAMTTO = by Mitra Ghassemzadeh; Masoomeh Tabatabaee; Mostafa M. Pooramini; Majid M. Heravi; Abbas Eslami; Bernhard Neumüller is a Chemistry article available to read on EtoBox.

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## Abstract The reaction of 4‐amino‐6‐methyl‐1,2,4‐triazin‐thione‐5‐one (H~2~AMTTO, 1) with 4‐chlorobenzaldhyde led to the corresponding iminic compound {(4‐[(4‐chloro‐benzylidene)‐amino]‐6‐methyl‐3‐thioxo[1,2,4]‐triazin‐3,4‐dihydro(2H)‐5‐one), CAMTTO (2). Treatment of 2 with copper(I) chloride in chloroform gave the dimeric complex [{(CAMTTO)~2~CuCl}~2~]·2CHCl~3~ (3). Treatment of 2 with copper(I) chloride and silver(I) nitrate in the presence of the co‐ligand triphenylphophane gave the complexes [(CAMTTO)CuCl(PPh~3~)~2~] (4) and [(CAMTTO)Ag(PPh~3~)~2~]NO~3~·2CHCl~3~ (5). All compounds have been characterized by elemental analyses, ^1^H NMR spectroscopy, IR spectroscopy, and partly by mass spectrometry and X‐ray diffraction studies. In addition 4 and 5 have been characterized by ^31^P{^1^H} NMR spectroscopy. Crystal data for 2 at −80 °C: monoclinic, space group P2~1~/c, a = 1370.3(1), b = 767.8(1), c = 1268.7(1) pm, β = 107.12(1)°, Z = 4, R~1~ = 0.0379; for 3 at −80 °C: monoclinic, space group P2~1~/c, a = 1442.6(2), b = 878.8(1), c = 2558.7(3) pm, β = 95.31(1)°, Z = 2, R~1~ = 0.0746; for 4 at −80 °C: triclinic, space group ${\rm P}{\bar 1}$, a = 1287.9(1), b = 1291.7(1), c = 1359

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Author

Mitra Ghassemzadeh; Masoomeh Tabatabaee; Mostafa M. Pooramini; Majid M. Heravi; Abbas Eslami; Bernhard Neumüller

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

2006

Language

EN

Field

Chemistry (Physical Sciences)