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Visualizing molecular orientational ordering and electronic structure in C60 fulleride films by Han, Sha; Guan, Meng-Xue; Song, Can-Li; Wang, Yi-Lin; Ren, Ming-Qiang; Meng, Sheng; Ma, Xu-Cun; Xue, Qi-Kun is a Physics and Astronomy article available to read on EtoBox.

What is Visualizing molecular orientational ordering and electronic structure in C60 fulleride films about?

Alkali-doped fullerides exhibit a wealth of unusual phases that remain controversial by nature. Here we report a cryogenic scanning tunneling microscopy study of the submolecular structural and electronic properties of expanded fullerene C n- 60 films with various cesium dopings. By varying the discrete charge states and film thicknesses, we reveal a large tunability of orientational ordering of C n- 60 anions, yet the tunneling conductance spectra are all robustly characteristic of energy gaps, hallmarks of Jahn-Teller instability and electronic correlations. The Fermi level lies halfway within the insulating gap for stoichiometric Cs doping level of n = 1, 2, 3, and 4, apart from which it moves toward band edges with concomitant electronic states within the energy gap. Our findings establish the universality of Jahn-Teller instability and clarify the relationship between the doping and structural and electronic properties in Cs n C 60 fullerides.

Who reads Visualizing molecular orientational ordering and electronic structure in C60 fulleride films?

It is typically read by researchers, students, and practitioners in Physics and Astronomy.

Author
Han, Sha; Guan, Meng-Xue; Song, Can-Li; Wang, Yi-Lin; Ren, Ming-Qiang; Meng, Sheng; Ma, Xu-Cun; Xue, Qi-Kun
Publisher
The American Physical Society; American Physical Society; Springer Verlag; American Physical Society (APS) (ISSN 1098-0121)
Published
2020
Language
EN
Field
Physics and Astronomy (Physical Sciences)

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