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Monomers for adhesive polymers, 2. Synthesis and radical polymerisation of hydrolytically stable acrylic phosphonic acids by Norbert Moszner; Frank Zeuner; Urs Karl Fischer; Volker Rheinberger is a Materials Science article available to read on EtoBox.

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Acrylic groups containing phosphonic acids were synthesised by ether formation of ethyl achloromethylacrylate with hydroxyalkylphosphonates and subsequent hydrolysis to the corresponding phosphonic acid a-methyl-substituted acrylates. The structure of the synthesised monomers was confirmed by elemental analysis, IR, 1 H NMR, 13 C NMR and 31 P NMR spectroscopy. The monomers are stable in aqueous ethanol. The radical polymerisation of the monoacrylates in tetrahydrofuran with 2,29-azobisisobutyronitrile (AIBN) results in soluble polymers, whereas a phosphonic acid diacrylate results in a cross-linked polymer.

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Author

Norbert Moszner; Frank Zeuner; Urs Karl Fischer; Volker Rheinberger

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1022-1352)

Published

1999

Language

EN

Field

Materials Science (Physical Sciences)