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Substituent Effects in the Gas-phase Eliminations of Alpha;-substituted Alkyl Chlorides the Pyrolyses of 2-Chloro-3-methylbutane and Pinacolyl Chloride by Gabriel Chuchani; Ignacio Martin; Miguel E. Alonso is a Chemistry article available to read on EtoBox.

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## Abstract The gas‐phase pyrolyses of 2‐chloro‐3‐methylbutane and pinacolyl chloride in the temperature range of 345‐390°C and pressure range of 60‐220 mm Hg are homogeneous and unimolecular in a seasoned reaction vessel. The temperature dependence of the rate constants is given by the Arrhenius equations and respectively. The Wagner‐Meerwein rearrangement was not observed in these eliminations. Some correlations for the pyrolysis of α‐substituted alkyl chlorides are presented and discussed. These facts are consistent with the heterolytic nature of the cyclic transition state mechanisms for these reactions.

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Author

Gabriel Chuchani; Ignacio Martin; Miguel E. Alonso

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0538-8066)

Published

1977

Language

EN

Field

Chemistry (Physical Sciences)