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Photocationic and radical polymerizations by novel N-phenacylammonium salts by Eiji Takahashi; Fumio Sanda; Takeshi Endo is a Materials Science article available to read on EtoBox.

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## Abstract Novel __N__‐phenacylammonium salts [__N__‐(α‐benzoylbenzyl)‐, __N__‐(1‐benzoylethyl)‐, __N__‐phenacyl‐, pyrazinium, 3‐bromoquinolinium, benzothiazolium, or __p__‐cyanopyridinium hexafluoroantimonates] were synthesized by the reaction of α‐benzoylbenzyl bromide, 2‐bromopropiophenone or phenacylbromide, and the corresponding __N__‐hetero aromatic compound, followed by anion exchange with KSbF~6~. These __N__‐phenacylammonium salts showed higher activity than previously reported __N__‐benzyl‐2‐cyanopyridinium hexafluoroantimonate in the photopolymerization of epoxides. Further, these __N__‐phenacylammonium salts served as photoradical and thermal cationic initiators as well as photocationic initiators. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3470–3476, 2004

Who reads Photocationic and radical polymerizations by novel N-phenacylammonium salts?

Author

Eiji Takahashi; Fumio Sanda; Takeshi Endo

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0021-8995)

Published

2004

Language

EN

Field

Materials Science (Physical Sciences)