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α-Man monolayer formation via Si–C bond formation and protein recognition by Koji Funato; Naoto Shirahata; Yoshiko Miura is a Engineering article available to read on EtoBox.

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An acetylenyl-terminated saccharide was synthesized and the thin layer formation on the hydrogen-terminated silicon was investigated. The acetylenyl-terminated saccharide was synthesized by the condensation reaction of hexynoic acid and p-aminophenyl saccharide. This was reacted with hydrogen-terminated silicon (Si-H) by a photochemical reaction. The resulting saccharide modified substrate was analyzed by ellipsometry and X-ray photoelectron spectroscopy, which showed the formation of a uniform monolayer. The surface's ability to recognize proteins was analyzed by fluorescent microscopy, and showed specific interactions with sugar recognition proteins.

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Author

Koji Funato; Naoto Shirahata; Yoshiko Miura

Publisher

Elsevier Science; Elsevier ; Elsevier Sequoia; Elsevier BV (ISSN 0040-6090)

Published

2009

Language

EL

Field

Engineering (Physical Sciences)