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A novel method for generation of carbenoid from α-chloro sulfoxides: A new and versatile procedure for one-carbon homologation of carbonyl compounds to carbonyl compounds having an α-alkyl substituent by Tsuyoshi Satoh; Norifumi Itoh; Kaoru Gengyo; Koji Yamakawa is a Chemistry article available to read on EtoBox.

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## Addition qf the carbanion of 1 -chkmalkyl p-tolyl sulfoxides to carbonyl compoundr gave the adducts, which were treated with a base folknved by t-butyllithium to #ord one-carbon homologated carbonyl compounds having an alkyd group at the a-position, via the &oxido carbenoi& in moderate to good yields. Homologation of carbonyl compounds from lower carbonyl compounds by carbon-carbon coupling is one of the most useful and reliable methods for obtaining desired carbonyl

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Author

Tsuyoshi Satoh; Norifumi Itoh; Kaoru Gengyo; Koji Yamakawa

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

1992

Language

EN

Field

Chemistry (Physical Sciences)