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Structure of CnCn+2Cn-type (n = even) β′-triacylglycerols by Arjen Van Langevelde; Kees Van Malssen; René Driessen; Kees Goubitz; Frank Hollander; René Peschar; Peter Zwart; Henk Schenk is a Chemistry article available to read on EtoBox.
What is Structure of CnCn+2Cn-type (n = even) β′-triacylglycerols about?
The crystal structures of the beta' phase of CLC (1, 3-didecanoyl-2-dodecanoylglycerol) and MPM (1, 3-ditetradecanoyl-2-hexadecanoylglycerol) have been determined from single-crystal X-ray diffraction and high-resolution X-ray powder diffraction data, respectively. Both these crystals are orthorhombic with space group Iba2 and Z = 8. The unit-cell parameters of beta'-CLC are a = 57.368 (6), b = 22.783 (2) and c = 5.6945 (6) A and the final R value is 0.175. The unit-cell parameters of beta'-MPM are a = 76.21 (4), b = 22.63 (1) and c = 5.673 (2) A and the final R(p) value is 0.057. Both the beta'-CLC and beta'-MPM molecules are crystallized in a chair conformation, having a bend at the glycerol moiety. The zigzag planes of the acyl chains are orthogonally packed, as is typical for a beta' phase. Furthermore, unit-cell parameters of some other members of the C(n)C(n+2)C(n)-type triacylglycerol series have been refined on their high-resolution X-ray powder diffraction pattern. Finally, the crystal structures are compared with the currently known structures and models of triacylglycerols.
Who reads Structure of CnCn+2Cn-type (n = even) β′-triacylglycerols?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Arjen Van Langevelde; Kees Van Malssen; René Driessen; Kees Goubitz; Frank Hollander; René Peschar; Peter Zwart; Henk Schenk
- Publisher
- International Union of Crystallography; Blackwell Publishing Inc.; International Union of Crystallography (IUCr) (ISSN 0108-7681)
- Published
- 2000
- Language
- EN
- Field
- Chemistry (Physical Sciences)