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Novel Synthesis of Alkenes via Triethylaluminum-induced Free Radical Reactions of Alkyl Iodides and β-Nitrostyrenes by Jing-Yuan Liu; Ju-Tsung Liu; Ching-Fa Yao is a Chemistry article available to read on EtoBox.
What is Novel Synthesis of Alkenes via Triethylaluminum-induced Free Radical Reactions of Alkyl Iodides and β-Nitrostyrenes about?
Reactions of (E)-b-nitrostyrenes 1 with triethylaluminum (Et 3 Al) 2 and alkyl iodide (RI) 3, 4, or 5 in the presence of benzoyl peroxide in diethyl ether solution at room temperature to give 60-100% of the different (E)-alkenes 6, 7, or 8. Under similar conditions, 95% of 1-adamantyl-2-(4-methoxyphenyl)ethene 10 or 80% of 1-(4-oxoadamantyl)-2-(4-methoxyphenyl)ethene 12 also can be easily prepared by using 1-iodoadamantane 9 or 5-iodo-2-adamantanone 11 and 2.
Who reads Novel Synthesis of Alkenes via Triethylaluminum-induced Free Radical Reactions of Alkyl Iodides and β-Nitrostyrenes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Jing-Yuan Liu; Ju-Tsung Liu; Ching-Fa Yao
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 2001
- Language
- EN
- Field
- Chemistry (Physical Sciences)