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Can I read Catalytic effects of activated carbon on hydrolysis reactions of chlorinated organic compounds: Part 1. γ-Hexachlorocyclohexane on EtoBox?
Catalytic effects of activated carbon on hydrolysis reactions of chlorinated organic compounds: Part 1. γ-Hexachlorocyclohexane by K. Mackenzie; J. Battke; F.-D. Kopinke is a Materials Science article available to read on EtoBox.
What is Catalytic effects of activated carbon on hydrolysis reactions of chlorinated organic compounds: Part 1. γ-Hexachlorocyclohexane about?
Dehydrochlorination of g-hexachlorocyclohexane (g-HCH or lindane) in aqueous solution in the presence of activated carbon (AC) was studied. Hydrolysis of lindane is accelerated in the presence of AC at moderate pH values, which is ascribed to a catalytic effect of the AC in the dehydrochlorination reaction. A novel reaction pathway leading to dichlorobenzenes was found in the presence of AC, whereas the hydrolysis in homogeneous solution stops at the stage of trichlorobenzenes. The contribution of the novel pathway to the overall reaction depends on the pH value. Indications for a slow neutral hydrolysis reaction were found. Conducting the hydrolysis in AC suspension with D 2 O/NaOD, no deuterium was found in the DCB formed, which implies that all hydrogen in the DCB originates from the parent molecule lindane. A hypothesis for the reaction mechanism is proposed.
Who reads Catalytic effects of activated carbon on hydrolysis reactions of chlorinated organic compounds: Part 1. γ-Hexachlorocyclohexane?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- K. Mackenzie; J. Battke; F.-D. Kopinke
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0920-5861)
- Published
- 2005
- Language
- EN
- Field
- Materials Science (Physical Sciences)