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Can I read A New Simple and Convenient Method for the Synthesis of Substituted 2,6,9-Trioxabicyclo[3.3.1]-nona-3,7-dienes from Arylmalondialdehydes on EtoBox?
A New Simple and Convenient Method for the Synthesis of Substituted 2,6,9-Trioxabicyclo[3.3.1]-nona-3,7-dienes from Arylmalondialdehydes by Anthony Fernandes; Jérôme Marrot; Jean-Pierre Gesson; Sébastien Papot is a Chemistry article available to read on EtoBox.
What is A New Simple and Convenient Method for the Synthesis of Substituted 2,6,9-Trioxabicyclo[3.3.1]-nona-3,7-dienes from Arylmalondialdehydes about?
A new convenient synthesis of substituted 2,6,9-trioxabicyclo[3.3.1]-nona-3,7-dienes is described. These new 'bridged bis-dioxines' were obtained in moderate to good yields by dimerization of the corresponding arylmalondialdehydes in the presence of 0.5 equiv of TMSOTf. The structure of the nitro derivative 1e has been proven by X-ray crystallography. A mechanism for this reaction is proposed.
Who reads A New Simple and Convenient Method for the Synthesis of Substituted 2,6,9-Trioxabicyclo[3.3.1]-nona-3,7-dienes from Arylmalondialdehydes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Anthony Fernandes; Jérôme Marrot; Jean-Pierre Gesson; Sébastien Papot
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 2006
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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