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Can I read Preparation of 2,6-difluoro-n-alkylbenzenes from 1,3-difluorobenzene Transformation of 2,6-difluorotoluene to the corresponding benzaldehyde via benzyl chloride on EtoBox?

Preparation of 2,6-difluoro-n-alkylbenzenes from 1,3-difluorobenzene Transformation of 2,6-difluorotoluene to the corresponding benzaldehyde via benzyl chloride by Evghenii V. Malykhin; Vitalii D. Shteingarts is a Chemistry article available to read on EtoBox.

What is Preparation of 2,6-difluoro-n-alkylbenzenes from 1,3-difluorobenzene Transformation of 2,6-difluorotoluene to the corresponding benzaldehyde via benzyl chloride about?

Reactions of n-alkyl chlorides with the 2,6-difluorophenyl anion prepared from 1,3-difluorobenzene by the action of sodium amide in liquid ammonia give 2,6-difluoro-n-alkylbenzenes in high yields. 2,6-Difluorotoluene reacts with chlorine at 80°C to give 2,6-difiuorobenzyl chloride in 92% yield. 2,6-Difluorobenzaldehyde has been obtained from this chloride through Sommelet's reaction in 62% yield.

Who reads Preparation of 2,6-difluoro-n-alkylbenzenes from 1,3-difluorobenzene Transformation of 2,6-difluorotoluene to the corresponding benzaldehyde via benzyl chloride?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
Evghenii V. Malykhin; Vitalii D. Shteingarts
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-1139)
Published
1998
Language
EN
Field
Chemistry (Physical Sciences)

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