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Binuclear hydrido platinum(II) complexes: syntheses of [{Pt(PP)}2(μ-CHCH2R)(μ-H)][BF4] (R=C6H5, H) and easy cleavage of a PC bond in a chelating 1,4-bis (diphenyl)phosphinobutane (PP) by Anna Laura Bandini; Guido Banditelli; Giovanni Minghetti is a Chemistry article available to read on EtoBox.
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Reactions of the binuclear platinum(II) trihydrido complex, [Pt 2 {(Ph 2 P) 2 (CH 2 ) 4 } 2 (H) 3 ][BF 4 ], with styrene or ethylene, at room temperature and low pressure, give m-alkylidene, m-hydrido cationic species together with an unexpected phosphido-bridged binuclear platinum(II) compound (3), originating from cleavage of a P C bond in the coordinated diphosphine. Complexes 1 -3 are discussed on the basis of FAB MS, IR and multinuclear NMR spectra in solution.
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- Author
- Anna Laura Bandini; Guido Banditelli; Giovanni Minghetti
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
- Published
- 2000
- Language
- EN
- Field
- Chemistry (Physical Sciences)