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Synthesis and stability of the complexes of the mixed-donor macrocycle 13-ANE-N2O2 by Vivienne J. Thöm; Robert D. Hancock is a Chemistry article available to read on EtoBox.
What is Synthesis and stability of the complexes of the mixed-donor macrocycle 13-ANE-N2O2 about?
We have previously reported [ 1, 21 the synthesis of mixed-donor macrocycles containing oxygen and nitrogen donor atoms and the structures of some of their complexes with metal ions [3, 41. We report here the synthesis of the novel macrocyclic ligand 1 3-aneNzOa (1,4-dioxa-7,ll -diazacyclotridecane) and the stability of its complexes with Cu(I1) and Zn(I1). This data can then be combined with that obtained previously for 13-aneNs (see Fig. for structure of ligands), and the literature [5] data on 13-aneN4, to gain a more complete picture of the effect of replacing nitrogen by oxygen donors on the complexing ability of the ligands.
Who reads Synthesis and stability of the complexes of the mixed-donor macrocycle 13-ANE-N2O2?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Vivienne J. Thöm; Robert D. Hancock
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)
- Published
- 1985
- Language
- EN
- Field
- Chemistry (Physical Sciences)