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Ammonia oxidation regimes and transitional behaviors in a Jet Stirred Flow Reactor by Maria Virginia Manna; Pino Sabia; Raffaele Ragucci; Mara de Joannon is a Engineering article available to read on EtoBox.

What is Ammonia oxidation regimes and transitional behaviors in a Jet Stirred Flow Reactor about?

The present work was devoted to the experimental identification of combustion regimes for NH 3 /O 2 mixtures diluted in N 2 in a Jet Stirred Flow Reactor (JSFR). Low Temperature (LT) combustion and High Temperature (HT) combustion regimes were identified as a function of reactor temperature (T r ) and mixture equivalence ratio ( φ). The shift between the identified regimes occurs at a noticeable system working temperature (1300 K), independently of the mixture composition. This shift may occur through a transitional Lower Reactivity (LR) regime for φ≤1 in-between 1300 and 1310 K. For fuel-lean conditions, damped temperature oscillations were recognized between 1310 and 1320 K. Different detailed kinetic mechanisms were used to simulate system reactivity. To some extent, kinetic models were able to reproduce the establishment of different kinetic regimes along with the dependence on system temperature and mixture composition. Kinetic analyses suggested that NH 2 oxidation routes control the shift between LT and HT regimes along with the establishment of dynamic behaviors. The experimental results obtained in this work represent important constraints for a fine tuning of ammonia chem

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Author
Maria Virginia Manna; Pino Sabia; Raffaele Ragucci; Mara de Joannon
Publisher
Elsevier BV
Published
2021
Language
EN
Field
Engineering (Physical Sciences)

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