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EXAFS study of iron coordination in intercalation compounds of titanium disulphide with iron and lithium by A.T. Shuvaev; B.Yu. Helmer; Ph.M. Ovsjannikov; A.S. Golub; Yu.N. Novikov; M.E. Vol'pin is a Physics and Astronomy article available to read on EtoBox.
What is EXAFS study of iron coordination in intercalation compounds of titanium disulphide with iron and lithium about?
The transition metal dichalcogenides and intercalated compounds fall into the category of two-dimensional solids in which there is a great deal of interest at present. The structural study [l] of the intercalated compounds TiS2 with Fe and Li shows the expansion in the c-direction: the sandwich (S-Ti-S) repeat distance along the c axis increases from 5.69 A in TiS2 to 5.71 8, in Feo.tSTiS:! (l), 6.11 8, in Lb.77Feo lsTiS2 (2) and 6.19 A in Lit\_oTiS2. After exposure to air the value of c in (2) decreases, this fact may be due to the Li removing from a van der Waals gap. EXAFS-spectra above the K-edge of Fe in the samples (l), ( 2) and ( 3) were recorded at room temperature at the in-lab spectrometer with varied curvature bent crystal [2]. The sample (3) is the one (2) exposured to air for a long time. The energy resolution
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- Author
- A.T. Shuvaev; B.Yu. Helmer; Ph.M. Ovsjannikov; A.S. Golub; Yu.N. Novikov; M.E. Vol'pin
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0921-4526)
- Published
- 1989
- Language
- EN
- Field
- Physics and Astronomy (Physical Sciences)