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Soluble and Fusible Polyamides and Polyimides Containing Pyrazoline Moieties and Their Crosslinking to Heat-resistant Resins by John A. Mikroyannidis is a Materials Science article available to read on EtoBox.

What is Soluble and Fusible Polyamides and Polyimides Containing Pyrazoline Moieties and Their Crosslinking to Heat-resistant Resins about?

3-(4-Aminophenyl)-5-(3-aminophenyl)-2-pyrazoline as well as the 1-acetyl-or 1-benzoyl-substituted derivatives of this compound were synthesized and used for preparing a new series of polyamides and polyimides. Characterization of polymers was accomplished by inherent viscosity, 1 H-NMR, 13 C-NMR, x-ray, DTA, TMA, TGA, and isothermal gravimetric analysis. The properties of polymers were correlated with their chemical structures. They were amorphous or microcrystalline and soluble in polar aprotic solvents, CCl 3 COOH, and m-cresol. The polyamides showed an excellent solubility being soluble even in o-dichlorobenzene, 1,2-dichloroethane, and chloroform. The polymers displayed T g at 127-163ЊC and softening at 150-195ЊC. The polyamide bearing unsubstituted pyrazoline moieties was remarkably more hydrophilic than those containing 1-acetyl-or 1-benzoyl-substituted pyrazoline segments. Upon curing, crosslinked polymers were obtained and their thermal stability was evaluated.

Who reads Soluble and Fusible Polyamides and Polyimides Containing Pyrazoline Moieties and Their Crosslinking to Heat-resistant Resins?

It is typically read by researchers, students, and practitioners in Materials Science.

Author
John A. Mikroyannidis
Publisher
John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-624X)
Published
1997
Language
EN
Field
Materials Science (Physical Sciences)

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