Opening book details…
Can I read Primary ^1^H/^2^H isotope effect in the NMR chemical shift of HClO~4~ salts of 1,8‐bis(dimethylamino)naphthalene derivatives on EtoBox?
Primary ^1^H/^2^H isotope effect in the NMR chemical shift of HClO~4~ salts of 1,8‐bis(dimethylamino)naphthalene derivatives by Piotr Chmielewski; Valery A. Ozeryanskii; Lucjan Sobczyk; Alexander F. Pozharskii is a Chemistry article available to read on EtoBox.
What is Primary ^1^H/^2^H isotope effect in the NMR chemical shift of HClO~4~ salts of 1,8‐bis(dimethylamino)naphthalene derivatives about?
## Abstract The primary ^1^H/^2^H isotope effect for a number of protonated naphthalene proton sponges (DMAN‐s) was measured and correlated with the __δ__(^1^H) value and IR spectroscopic characteristics of the [NHN]^+^ hydrogen bonds. A particular role of the unusual anharmonicity expressed in the isotopic ratio ISR ≫$\sqrt 2 $ is discussed when the fundamental vibrational levels are close to the barrier top for proton/deuteron motion. Copyright © 2007 John Wiley & Sons, Ltd.
Who reads Primary ^1^H/^2^H isotope effect in the NMR chemical shift of HClO~4~ salts of 1,8‐bis(dimethylamino)naphthalene derivatives?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Piotr Chmielewski; Valery A. Ozeryanskii; Lucjan Sobczyk; Alexander F. Pozharskii
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0894-3230)
- Published
- 2007
- Language
- EN
- Field
- Chemistry (Physical Sciences)