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Transfer hydrogenation of nitroarenes using cellulose filter paper-supported Pd/C by filtration as well as sealed methods by Bokov, Dmitry Olegovich (author);Mahmoud, Mustafa Z. (author);Widjaja, Gunawan (author);Suksatan, Wanich (author);Chupradit, Supat (author);Altimari, Usama S. (author);Hussein, Hussein Ali (author);Mustafa, Yasser Fakri (author);kazemnejadi, Milad (author) is a Materials Science article available to read on EtoBox.
What is Transfer hydrogenation of nitroarenes using cellulose filter paper-supported Pd/C by filtration as well as sealed methods about?
A reductive filter paper for selective nitro reduction has been prepared by modification of a pristine cellulose filter paper by Pd/C nanoparticles, as a portable catalyst. The reaction was performed in two different set-ups including (i) filtration and (ii) sealed systems, in the presence of ammonium formate and generated hydrogen gas reducing agents, respectively. In the sealed system in the presence of H gas, the halogenated nitroarenes were completely reduced, while in the filtration system, different derivatives of the nitroarenes were selectively reduced to aryl amines. In both systems, the reduction of nitroarenes to aryl amines was performed with high efficiency and selectivity, comparable to a heterogeneous system. Reaction parameters were comprehensively designed using Design Expert software and then studied. The properties of the catalytic filter paper were studied in detail from the points of view of swellability, shrinkage, reusability, and stability against acidic, alkaline, and oxidative reagents.
Who reads Transfer hydrogenation of nitroarenes using cellulose filter paper-supported Pd/C by filtration as well as sealed methods?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Bokov, Dmitry Olegovich (author);Mahmoud, Mustafa Z. (author);Widjaja, Gunawan (author);Suksatan, Wanich (author);Chupradit, Supat (author);Altimari, Usama S. (author);Hussein, Hussein Ali (author);Mustafa, Yasser Fakri (author);kazemnejadi, Milad (author)
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2022
- Language
- EN
- Field
- Materials Science (Physical Sciences)