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Mediated Electrochemistry of Peroxidases—effects of Variations in Protein and Mediator Structures by S.J. Sadeghi; G. Gilardi; A.E.G. Cass is a Engineering article available to read on EtoBox.

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The kinetics of a range of ferrocene derivatives with horseradish peroxidase (HRP), cytochrome c peroxidase (CCP) and 3 charge reversal mutants of cytochrome c peroxidase were measured using cyclic voltammetry. Substantial differences in rate constant (100 fold) were observed between HRP and CCP for the same mediator with smaller differences (4-5 fold) for different mediators with the same enzyme. The rate constant did not seem to be dependent on redox potential differences. Cluster analysis is proposed as a way of classifying mediator reactivity.

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Author

S.J. Sadeghi; G. Gilardi; A.E.G. Cass

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0956-5663)

Published

1997

Language

EN

Field

Engineering (Physical Sciences)