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Adducts of nickel(II) acetylacetonate chelating with heterocyclic bases: 3-­cyanopyridine and 4-cyanopyridine by J. Zukerman-Schpector; Antonio Carlos Trindade; P. O. Dunstan is a Chemistry article available to read on EtoBox.

What is Adducts of nickel(II) acetylacetonate chelating with heterocyclic bases: 3-­cyanopyridine and 4-cyanopyridine about?

In both title compounds, (acetylacetonato-O,O H )bis(3-cyanopyridine-N)nickel(II), (I), and (acetylacetonato-O,O H )bis-(4-cyanopyridine-N)nickel(II), (II), both [Ni(C 5 H 7 O 2 ) 2 -(C 6 H 4 N 2 ) 2 ], the Ni II atom, which is situated on a centre of symmetry, is octahedrally coordinated. Distances and angles for (I) and (II), respectively, are: NiÐO 2.009 (2)/2.016 (2) and 2.0110 (16)/2.0238 (18) A Ê , NiÐN 2.116 (3) and 2.179 (2) A Ê , OÐNiÐO 91.86 (10) and 90.19 (7) , and OÐ NiÐN 91.27 (11)/90.19 (11) and 89.65 (8)/90.79 (7) .

Who reads Adducts of nickel(II) acetylacetonate chelating with heterocyclic bases: 3-­cyanopyridine and 4-cyanopyridine?

Author

J. Zukerman-Schpector; Antonio Carlos Trindade; P. O. Dunstan

Publisher

International Union of Crystallography; Blackwell Publishing Inc.; International Union of Crystallography (IUCr); Wiley (ISSN 0108-2701)

Published

2000

Language

EN

Field

Chemistry (Physical Sciences)