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Tailoring Discotic Mesophases: Columnar Order Enforced with Hydrogen Bonds by R.I. Gearba; M. Lehmann; J. Levin; D.A. Ivanov; M.H.J. Koch; J. Barberá; M.G. Debije; J. Piris; Y.H. Geerts is a Engineering article available to read on EtoBox.

**Hydrogen bonding can be used to significantly enforce** the intra‐columnar stacking order in discotic mesogens. The ordered hexagonal columnar mesophase of a HAT‐CONHR derivative is characterized by the smallest inter‐disk distance ever found in columnar liquid crystals (3.18–3.20 Å). This additional attractive interaction between the disks in the column results in a regular disc stacking and thus in a high charge‐carrier mobility over the whole investigated temperature range (from room temperature up to 200 °C).

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Author
R.I. Gearba; M. Lehmann; J. Levin; D.A. Ivanov; M.H.J. Koch; J. Barberá; M.G. Debije; J. Piris; Y.H. Geerts
Publisher
John Wiley and Sons; Wiley (John Wiley & Sons); Wiley-Blackwell; Wiley; Research Square (ISSN 0935-9648)
Published
2003
Language
EN
Field
Engineering (Physical Sciences)