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Stereoselective conversion of D-glucuronolactone into pseudo-sugar: Syntheses of pseudo -α-D-glucopyranose, pseudo-β-D-glucopyranose, and validamine by Masayuki Yoshikawa; Nobutoshi Murakami; Yoshihiro Yokokawa; Yasunao Inoue; Yasuyuki Kuroda; Isao Kitagawa is a Chemistry article available to read on EtoBox.
What is Stereoselective conversion of D-glucuronolactone into pseudo-sugar: Syntheses of pseudo -α-D-glucopyranose, pseudo-β-D-glucopyranose, and validamine about?
TWO optically active pseudo-sugars, pseudo-a-D-gluse (12) and pse&~Bglucqyra~~~ (13). were synthesized from D-glucuronolactonc in favorable overall yields by using a stereoselective nimunethane addition reaction and a reductive elimination of an ethoxyethoxyl moiety with NaBH4 as key steps. Furthermore, a biologically active pseudo-aminosugar, validamine (18) was efficiently synthesii via a substitution reaction for an acetoxyl group at the fl-position of nitro group in a nitrocyclitol derivative (14) which was prepared from a synthetic intermediate (9) of psclcdo-D-glucopyranoses (12.13).
Who reads Stereoselective conversion of D-glucuronolactone into pseudo-sugar: Syntheses of pseudo -α-D-glucopyranose, pseudo-β-D-glucopyranose, and validamine?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Masayuki Yoshikawa; Nobutoshi Murakami; Yoshihiro Yokokawa; Yasunao Inoue; Yasuyuki Kuroda; Isao Kitagawa
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 1994
- Language
- EN
- Field
- Chemistry (Physical Sciences)