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Synthesis and Self-assembly Properties of Para-acyl-calix[8]arenes by Saïd Jebors; Gennady S. Ananchenko; Anthony W. Coleman; John A. Ripmeester is a Chemistry article available to read on EtoBox.

What is Synthesis and Self-assembly Properties of Para-acyl-calix[8]arenes about?

The synthesis of a series of novel para-acyl-calix[8]arenes is described, while for acyl chain lengths of greater than eight carbon atoms total substitution at the para position occurs, in contrast to the para-acyl-calix[4]arenes, some esterification at the phenolic face may also occur, particularly for shorter acyl chain lengths. Simple saponification with potassium hydroxide in ethanol allows the pure compounds to be obtained in good yields. All the derivatives show amphiphilic behaviour with formation of stable monolayers at the air-water interface and apparent molecular areas between 150 and 275 A ̊2.

Who reads Synthesis and Self-assembly Properties of Para-acyl-calix[8]arenes?

Author

Saïd Jebors; Gennady S. Ananchenko; Anthony W. Coleman; John A. Ripmeester

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

2007

Language

EN

Field

Chemistry (Physical Sciences)