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Synthesis, structure and characterization of 1D threefold-bridging copper(II) chain with strong ferromagnetic coupling by Qiao-Juan Su; Shao-Hua Li; Li Wang; Cheng-Zhi Xie; Yan Ouyang; Jing-Yuan Xu is a Materials Science article available to read on EtoBox.

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A 1D chain Cu(II) complex: [Cu(2-Clnic)(μ 1,1 -N 3 )(CH 3 OH)] n (1) (2-Clnic=2-chloronicotinate) has been synthesized and characterized by IR, elemental analysis, X-ray crystal diffraction and magnetic properties. Single-crystal structural analysis shows that complex 1 consists of 1D Cu(II) chains containing threefold bridging ligands, one μ 1,1 -azido, one (syn-syn) 2-chloronicotinate and one methanol molecule. The magnetic susceptibilities of 1 has been investigated, indicating strong ferromagnetic interactions with J = 81.22 cm -1 .

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Author

Qiao-Juan Su; Shao-Hua Li; Li Wang; Cheng-Zhi Xie; Yan Ouyang; Jing-Yuan Xu

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 1387-7003)

Published

2010

Language

EN

Field

Materials Science (Physical Sciences)