Opening book details…
Can I read Asymmetric Tandem Michael-Aldol Reactions between 3-Cinnamoyloxazolidine-2-thiones and Aldehydes on EtoBox?
Asymmetric Tandem Michael-Aldol Reactions between 3-Cinnamoyloxazolidine-2-thiones and Aldehydes by Hironori Kinoshita; Takashi Osamura; Kazumi Mizuno; Sayaka Kinoshita; Tatsunori Iwamura; Shin-ichi Watanabe; Tadashi Kataoka; Osamu Muraoka; Genzoh Tanabe is a Chemistry article available to read on EtoBox.
What is Asymmetric Tandem Michael-Aldol Reactions between 3-Cinnamoyloxazolidine-2-thiones and Aldehydes about?
## Abstract Reactions between chiral 3‐cinnamoyl‐4‐methyl‐5‐phenyl‐1,3‐oxazolidine‐2‐thiones and aromatic aldehydes in the presence of BF~3~⋅Et~2~O diastereoselectively produced tricyclic compounds incorporating a bridgehead carbon bound to four heteroatoms in high yields. Four stereocenters were induced during the reaction. The tricyclic products were transformed into propane‐1,3‐diols bearing three consecutive stereocenters by acid hydrolysis, __S__‐methylation, and reductive removal of the chiral auxiliary.
Who reads Asymmetric Tandem Michael-Aldol Reactions between 3-Cinnamoyloxazolidine-2-thiones and Aldehydes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Hironori Kinoshita; Takashi Osamura; Kazumi Mizuno; Sayaka Kinoshita; Tatsunori Iwamura; Shin-ichi Watanabe; Tadashi Kataoka; Osamu Muraoka; Genzoh Tanabe
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 0947-6539)
- Published
- 2006
- Language
- EN
- Field
- Chemistry (Physical Sciences)