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Asymmetric polymers. XXVI. Optically active polyamides: (–)poly‐( S )‐4‐ tert ‐butoxymethyl‐ and 4‐hydroxymethyl‐6‐hexanamide by C. G. Overberger; John H. Kozlowski is a Materials Science article available to read on EtoBox.

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## Abstract Racemic and optically active hexahydro‐5‐__tert__‐butoxymethyl‐2__H__‐azepin‐2‐one were polymerized, and the resulting poly‐4‐__tert__‐butoxymethyl‐6‐hexanamides were treated to remove the __tert__‐butyl protective group. ORD and CD spectra of (–)‐poly‐(__S__)‐4‐__tert__‐butoxymethyl‐6‐hexanamide and (–)poly‐(__S__)‐4‐hydroxymethyl‐6‐hexanamide were compared with spectra of their low molecular weight models, (__S__)(–)‐6‐acetamido‐4‐__tert__‐butoxymethyl‐__N__‐methylhexanamide and (__S__)( – )‐6‐acetamido‐4‐hydroxymethyl‐__N__‐methylhexanamide, in 2,2,2‐trifluoroethanol, __p__‐dioxane–water mixtures, and methanol–water mixtures.

Who reads Asymmetric polymers. XXVI. Optically active polyamides: (–)poly‐( S )‐4‐ tert ‐butoxymethyl‐ and 4‐hydroxymethyl‐6‐hexanamide?

Author

C. G. Overberger; John H. Kozlowski

Publisher

Wiley (John Wiley & Sons); Interscience Publishers; Wiley (ISSN 0449-296X)

Published

1972

Field

Materials Science (Physical Sciences)