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Can I read Asymmetric Allylic Oxidation with Biarylbisoxazoline-Copper(I) Catalysis on EtoBox?
Asymmetric Allylic Oxidation with Biarylbisoxazoline-Copper(I) Catalysis by Merritt B Andrus; Davoud Asgari is a Chemistry article available to read on EtoBox.
What is Asymmetric Allylic Oxidation with Biarylbisoxazoline-Copper(I) Catalysis about?
AbstractÐEight new bi-o-tolyl bisoxazolines were made and used as ligands in the copper catalyzed asymmetric allylic oxidation reaction. Three benzoyl tert-butyl peresters, p-nitro, o-iodo, and 2,4,6-trichloro were made and used with cyclohexene and cyclopentene with the ligands complexed to copper(I) hexa ̄uorophosphate (10 mol%). High selectivities (73% ee, 78% yield) were obtained with the nitroperester and 1a (S,S,S RPh) and cyclohexene. For the cyclopentene, 1c (RBn) was best at 72% ee, 63% yield.
Who reads Asymmetric Allylic Oxidation with Biarylbisoxazoline-Copper(I) Catalysis?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Merritt B Andrus; Davoud Asgari
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 2000
- Language
- EN
- Field
- Chemistry (Physical Sciences)