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Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles by Hyung Yoon is a nonfiction available to read on EtoBox.

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This book presents Pd- and Ni-catalyzed transformations generating functionalized heterocycles. Transition metal catalysis is at the forefront of synthetic organic chemistry since it offers new and powerful methods to forge carbon–carbon bonds in high atom- and step-economy. In Chapter 1, the author describes a Pd- and Ni-catalyzed cycloisomerization of aryl iodides to alkyl iodides, known as carboiodination. In the context of the Pd-catalyzed variant, the chapter explores the production of enantioenriched carboxamides through diastereoselective Pd-catalyzed carboiodination. It then discusses Ni-catalyzed reactions to generate oxindoles and an enantioselective variant employing a dual ligand system. Chapter 2 introduces readers to a Pd-catalyzed diastereoselective anion-capture cascade. It also examines diastereoselective Pd-catalyzed aryl cyanation to synthesize alkyl nitriles, a method that generates high yields of borylated chromans as a single diastereomer, and highlights its synthetic utility.   Lastly, Chapter 3 presents a Pd-catalyzed domino process harnessing carbopalladation, C–H activation and π-system insertion (benzynes and alkynes) to generate spirocycles. It also desc

Who reads Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles?

Author

Hyung Yoon

Publisher

Springer International Publishing : Imprint: Springer

Published

2020

Language

EN

ISBN

9783030540777

Category

nonfiction

Subjects

Science, Chemistry, Stem