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Possible role of Lewis acid catalysis in the oxidation of alkenes and α,β-unsaturated ketones using bleomycin-zn(ii) and bleomycin-fe(iii)-iodosylbenzene in aqueous methanol by Robert M. Moriarty; Raju Penmasta; Indra Prakash is a Chemistry article available to read on EtoBox.

What is Possible role of Lewis acid catalysis in the oxidation of alkenes and α,β-unsaturated ketones using bleomycin-zn(ii) and bleomycin-fe(iii)-iodosylbenzene in aqueous methanol about?

CeH510 in CH30H-HZ0 is activated towards electrophilic attack upon various alkenes by Fe(C104)'9H20, Fe(II1) bleomycin and Zn(I1) bleomycin. The results imply that direct transfer of oxygen from an Fe(V)=0 intermediate is not required in the mechanism of oxygenation by iron-containing species, and that much earlier work is questionable as models for biological oxygenation.

Who reads Possible role of Lewis acid catalysis in the oxidation of alkenes and α,β-unsaturated ketones using bleomycin-zn(ii) and bleomycin-fe(iii)-iodosylbenzene in aqueous methanol?

Author

Robert M. Moriarty; Raju Penmasta; Indra Prakash

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

1985

Language

EN

Field

Chemistry (Physical Sciences)