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What is Ligand Field Theory and d-Orbital Splitting about?

This document summarizes electronic transitions that could occur in an octahedral d3 complex and assigns vibrational modes of an octahedral complex. It then analyzes the electronic spectra of four Cr(III) complexes, assigning transitions and ordering ligands based on ligand field theory. Finally, it discusses two-photon experiments on Cr(III) complexes and efforts to parameterize d-d spectra through molecular orbital theory.

Author

Joakin Bahamondes

Language

EN