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Can I read Synthesis Of New Carborane-containing Ketones. Novel Dehydrocyanation Reaction Involving Boron Hydrides on EtoBox?
Synthesis Of New Carborane-containing Ketones. Novel Dehydrocyanation Reaction Involving Boron Hydrides by Iwona M. Wyzlic; Albert H. Soloway is a Chemistry article available to read on EtoBox.
What is Synthesis Of New Carborane-containing Ketones. Novel Dehydrocyanation Reaction Involving Boron Hydrides about?
A novel dehydrocyanation reaction involving boron hydrides is described. This reaction has been applied to the synthesis of new boronated ketones: di(o-carboran-1-ylmethyl)ketone (8a) and (o-carboran-l-ylmethyl)benzylketone (fib). The stepwise alkylation of commerciallyavailable N-(diphenylmethylene)aminoacetonitrile yielded a,a-disubstituted-[N-(diphenylmethylene)]aminoacetonitriles, 4, which, when reacted with decaborane-acetonitrile complex, undergoes the elimination of hydrogen cyanide. The acid hydrolysis of these dehydrocyanation products, 3. afforded the corresponding ketones, g.
Who reads Synthesis Of New Carborane-containing Ketones. Novel Dehydrocyanation Reaction Involving Boron Hydrides?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Iwona M. Wyzlic; Albert H. Soloway
- Published
- 1996
- Language
- EN
- Field
- Chemistry (Physical Sciences)