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⋅ DABCO ⋅ 1.66 CH~2~Cl~2~: Cluster Units Wrapped in a Network of Hydrogen Bonds by Eric Sperlich; Martin Köckerling is a Chemistry article available to read on EtoBox.
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## Abstract An easy‐to‐do synthesis for the hexanuclear niobium cluster compound [Nb~6~Cl~12~(CH~3~OH)~4~(OCH~3~)~2~] ⋅ DABCO ⋅ 1.66 CH~2~Cl~2~ has been developed. An one‐pot reaction between the cluster precursor [Nb~6~Cl~14~(H~2~O)~4~] ⋅ 4H~2~O and methanol with the addition of DABCO leads to the crystallization of the title compound in high yield within a few minutes. The single‐crystal X‐ray structure of this cluster compound has been determined. Very strong, nearly symmetric intercluster hydrogen bonds Nb~6~−MeO⋅⋅⋅H⋅⋅⋅OMe−Nb~6~ are present between the cluster units. A bridging co‐crystalline DABCO molecule is also involved in a three‐dimensional hydrogen‐bonding network.
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- Author
- Eric Sperlich; Martin Köckerling
- Publisher
- Wiley
- Published
- 2021
- Language
- EN
- Field
- Chemistry (Physical Sciences)