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PMR and thermodynamic studies of dimethyltin dichloride/picolinaldimine adducts by Gen-Etsu Matsubayashi; Masaaki Okunaka; Toshio Tanaka is a Chemistry article available to read on EtoBox.

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Stable diiethyltin dichloride adducts with several picolinaldimines (C,H,-NCH=NR, R= CH3, C,H40CH,-p, C6H4CH3-p, C,H,Cl-p) have been isolated and the configurations in solution have been discussed on the basis of PMR spectra of the complexes. Equilibrium constants of the adducts in acetonitrile have been determined from the "'Sn-CH, coupling constants of dimethyltin dichloride. Heats of complex formation in acetonitrile have also been measured by calorimetry, and thermodynamic parameters in the complex formation have been obtained. \* Cbem. Abstr.

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Author

Gen-Etsu Matsubayashi; Masaaki Okunaka; Toshio Tanaka

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1973

Language

EN

Field

Chemistry (Physical Sciences)