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Research on the electrochemical degradation and hydrogen generation of Fraxinus mandshurica by polyoxometalate by Jiayue Ma; Fengrong Gong; Xiuyuan Ma; Lihui Jiang; Ting Wang is a Engineering article available to read on EtoBox.

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The efficient utilization of wood waste is important for protecting the environment and solving the energy shortage problem. Taking Fraxinus mandshurica (FM) as an example, polyoxometalate (POM) was used as a catalyst for cyclic redox in an H-type electrolytic cell, where wood was oxidized to valuable smallmolecule chemicals at the anode and hydrogen was generated at the cathode. The system successfully recycles energy, simultaneously converting biomass to chemical and electrical to hydrogen. Furthermore, the effects of various factors on the reaction were also investigated to obtain the optimal electrochemical conversion results for wood waste. At the optimal conditions, the FM degradation rate of 56.1%, with aromatic organic and carbonyl compounds as the main products, and the average Faraday efficiency of hydrogen generation can reach 93%, saving about 40% of energy consumption compared to water electrolysis at 0.1 A cm −2 . Therefore, this electrochemical conversion method provides a new potential pathway for the application of wood waste.

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Author

Jiayue Ma; Fengrong Gong; Xiuyuan Ma; Lihui Jiang; Ting Wang

Publisher

Informa UK Limited

Published

2023

Language

EN

Field

Engineering (Physical Sciences)