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Characterization of (E,E)-farnesol and its fatty acid esters from anal scent glands of nutria (Myocastor coypus) by gas chromatography–mass spectrometry and gas chromatography–infrared spectrometry by Hyeunjoo Lee; Steven Finckbeiner; Jose S. Yu; David F. Wiemer; Thomas Eisner; Athula B. Attygalle is a Chemistry article available to read on EtoBox.

What is Characterization of (E,E)-farnesol and its fatty acid esters from anal scent glands of nutria (Myocastor coypus) by gas chromatography–mass spectrometry and gas chromatography–infrared spectrometry about?

Several volatile compounds, including terpenoids, fatty alcohols, fatty acids and some of their esters, were identified from solvent extracts prepared from anal scent glands of nutria (a.k.a. coypu), a serious rodent pest ravaging wetlands in the USA. The major terpenoid constituents were identified as (E,E)-farnesol and its esters by a comparison of their gas chromatographic retention times, and electron-ionization (EI) and chemical-ionization (CI) mass spectra with those of authentic compounds. EI mass spectra of the four farnesol isomers are very similar, however, the ChemStation (Agilent) and GC-MS Solution (Shimadzu) software algorithms were able to identify the natural compound as the (E,E)-isomer, when a high-quality mass spectral library was compiled from reference samples and used for searching. Similarly, the esters were identified as those of (E,E)-farnesol. In contrast to EI spectra, the CI spectra of the (E,E)-and (E,Z)-isomers are distinctly different from those of the (Z,E)-and (Z,Z)-isomers. The intensities (I) of the peaks for the m/z 137 and 121 ions in the CI spectra offer a way of determining the configuration of the C-2 double bond of farnesols (for 2E isomers

Who reads Characterization of (E,E)-farnesol and its fatty acid esters from anal scent glands of nutria (Myocastor coypus) by gas chromatography–mass spectrometry and gas chromatography–infrared spectrometry?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
Hyeunjoo Lee; Steven Finckbeiner; Jose S. Yu; David F. Wiemer; Thomas Eisner; Athula B. Attygalle
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 1873-3778)
Published
2007
Language
EN
Field
Chemistry (Physical Sciences)

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