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The cover picture shows a ball-and-stick model of the first peroxocopper(i1) complex [C~,L,(O,)(OML.)~(CIO,~] ' ( L = anion of the tridentate ligand 4-methyI-2,6-bis-(pyrrolidinoniethy1)phen~~l) stable at room temperature. This cation (color code: Cu brown, 0 rcd. N blue. C black. CI green) is characterized by several unusual structural details. including ii p,-bridging 0, ligand and a C10, ligand bound unsymmetrically to the c'u, center. The picture was produced with the program POV-Ray on an IHM Workstation by Dipl.-Chem. S. J. Schindler. Further information on the structural and spectroscopic properties of this compound, which are of general interest for biochemistry :ind coordination chemistry, are reported by B. Krebs and J. Reiin o n pages 1969ff. HIGHLIGHTS Contents Molecular structures can perform diverse functions. Tailored bolaamphiphiles were G. H. Escamilla, used to prepare vesicles containing redox-active centers or (chiral) binding sites G. R. Newkome\* .

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Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley; Research Square (ISSN 0044-8249)

Published

1994

Language

EN

Field

Chemistry (Physical Sciences)